An efficient portfolio is one that provides the
greatest expected return for a given level of risk, or equivalently,
the lowest risk for a given expected return.
The science of risk-efficient portfolios is associated with a
couple of Nobel laureates named Harry Markowitz and Bill Sharpe.
Suppose you have data for a collection of securities (like the
S&P 500 stocks, for example), and you graph the return rates
and standard deviations (a statistical measure of the historical
volatility of a portfolio). Markowitz showed that you get a region
bounded by an upward-sloping curve, which he called the efficient
frontier.
It's clear that for any given value of standard deviation, you
would like to choose a portfolio that gives you the greatest possible
rate of return; so you always want a portfolio that lies up along
the efficient frontier, rather than lower down, in the interior
of the region. This is the first important property of the efficient
frontier: it's where the best portfolios are.